most likely doing the plesk 9.3.0 update today stopped midway and messed up email perms.  we kept getting the error

Technical details of permanent failure:
Google tried to deliver your message, but it was rejected by the recipient domain. We recommend contacting the other email provider for further information about the cause of this error. The error that the other server returned was: 550 550 #5.1.0 Address rejected james@stuffthatspins.com (state 14).

fix plesk mail perms
http://kb.parallels.com/en/944

/usr/local/psa/var/log$ /usr/local/psa/admin/sbin/mchk –with-spam